HistCite - Publications by EI Negishi

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#	Date / Author / Journal	LCS	GCS	LCR	CR
51	47 Negishi EI, KULKARNI SU, BROWN HC ORGANOBORANE HETEROCYCLES VIA CYCLIC HYDROBORATION OF DIENES HETEROCYCLES. 1976; 5: 883-904	1	8	7	43
52	246 Negishi EI, Kondakov DY, Choueiry D, Kasai K, et al. Multiple mechanistic pathways for zirconium-catalyzed carboalumination of alkynes. Requirements for cyclic carbometalation processes involving C-H activation JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1996 OCT 9; 118 (40): 9577-9588	14	60	15	43
53	349 Qian MX, Huang ZH, Negishi EI Use of lnCl(3) as a cocatalyst and a Cl2Pd(DPEphos)-P(2-Furyl)(3) catalyst system for one-pot hydrometalation-cross-coupling and carbometalation-cross-coupling tandem processes ORGANIC LETTERS. 2004 MAY 13; 6 (10): 1531-1534	4	27	13	43
54	201 TAKAHASHI T, HASEGAWA M, SUZUKI N, SABURI M, et al. ZIRCONIUM-CATALYZED, HIGHLY REGIOSELECTIVE HYDROSILATION REACTION OF ALKENES AND X-RAY STRUCTURES OF SILYL(HYDRIDO)ZIRCONOCENE DERIVATIVES JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1991 OCT 23; 113 (22): 8564-8566	2	107	9	41
55	302 Anastasia L, Negishi EI Highly satisfactory procedures for the Pd-catalyzed cross coupling of aryl electrophiles with in situ generated alkynylzinc derivatives ORGANIC LETTERS. 2001 OCT 4; 3 (20): 3111-3113	3	40	18	41
56	336 Shi JC, Zeng XZ, Negishi EI Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd((Bu3P)-Bu-t)(2) ORGANIC LETTERS. 2003 MAY 29; 5 (11): 1825-1828	11	35	4	40
57	353 Zeng XZ, Zeng FX, Negishi EI Efficient and selective synthesis of 6,7-dehydrostipiamide via Zr-catalyzed asymmetric carboalumination and Pd-catalyzed cross-coupling of organozincs ORGANIC LETTERS. 2004 SEP 16; 6 (19): 3245-3248	6	17	15	40
58	89 MATSUSHITA H, Negishi EI SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS .18. PALLADIUM-CATALYZED STEREOSPECIFIC AND REGIOSPECIFIC COUPLING OF ALLYLIC DERIVATIVES WITH ALKENYLMETALS AND ARYLMETALS - A HIGHLY SELECTIVE SYNTHESIS OF 1,4-DIENES JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1981; 103 (10): 2882-2884	25	93	13	39
59	170 WU GZ, LAMATY F, Negishi EI METAL-PROMOTED CYCLIZATION .26. PALLADIUM-CATALYZED CYCLIZATION OF BENZYL HALIDES AND RELATED ELECTROPHILES CONTAINING ALKENES AND ALKYNES AS A NOVEL ROUTE TO CARBOCYCLES JOURNAL OF ORGANIC CHEMISTRY. 1989 MAY 26; 54 (11): 2507-2508	8	69	5	39
60	247 Negishi EI, Liu F, Choueiry D, Mohamud MM, et al. Convenient and general synthesis of 1-monoorganyl-and 1,2-diorganylcyclobutenes via cyclialkylation JOURNAL OF ORGANIC CHEMISTRY. 1996 NOV 15; 61 (23): 8325-8328	3	20	12	39
#	Date / Author / Journal	LCS	GCS	LCR	CR
61	285 Akira K, Negishi EI, Sakuma C, Hashimoto T Direct detection of antipyrine metabolites in rat urine by C-13 labeling and NMR spectroscopy DRUG METABOLISM AND DISPOSITION. 1999 NOV; 27 (11): 1248-1253	1	6	1	39
62	379 Huang ZH, Negishi EI Highly stereo-and regioselective synthesis of (Z)-trisubstituted Alkenes via 1-bromo-1-alkyne hydroboration-migratory insertion-Zn-promoted iodinolysis and Pd-catalyzed organozinc cross-coupling JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2007 NOV 28; 129 (47): 14788-14792	2	4	11	39
63	218 TAKAHASHI T, AOYAGI K, DENISOV V, SUZUKI N, et al. ZIRCONIUM CATALYZED C-C BOND FORMATION REACTION OF CONJUGATED DIYNES WITH ETMGBR TETRAHEDRON LETTERS. 1993 DEC 17; 34 (51): 8301-8304	3	29	17	38
64	343 Dumond YR, Negishi EI Zr-promoted 'pair'-selective and regioselective synthesis of penta-substituted benzene derivatives TETRAHEDRON. 2004 FEB 2; 60 (6): 1345-1352	1	3	10	38
65	384 Wang GW, Huang ZH, Negishi EI Efficient and selective syntheses of (all-E)- and (6E,10Z)-2 '-O-Methylmyxalamides D via Pd-catalyzed alkenylation-carbonyl olefination synergy ORGANIC LETTERS. 2008 AUG 7; 10 (15): 3223-3226	1	1	11	38
66	385 Xu Z, Negishi EI Efficient and stereoselective synthesis of yellow scale pheromone via alkyne haloboration, Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction), and Pd-catalyzed tandem Negishi coupling ORGANIC LETTERS. 2008 OCT 2; 10 (19): 4311-4314	0	0	19	38
67	138 BROWN HC, BASAVAIAH D, KULKARNI SU, LEE HD, et al. VINYLIC ORGANOBORANES .6. A GENERAL-SYNTHESIS OF (E)-DISUBSTITUTED ALKENES OR KETONES VIA THE (E)-(1-SUBSTITUTED-1-ALKENYL)BORONIC ESTERS JOURNAL OF ORGANIC CHEMISTRY. 1986 DEC 26; 51 (26): 5270-5276	0	22	5	37
68	255 Negishi EI, Ma SM, Sugihara T, Noda Y Synthesis of hydrazulenes via Zr-promoted bicyclization of enynes and transition metal-catalyzed or radical cyclization of alkenyl iodides. Efficient synthesis of (+/-)-7-epi-beta-bulnesene JOURNAL OF ORGANIC CHEMISTRY. 1997 APR 4; 62 (7): 1922-1923	1	25	11	37
69	373 Metay E, Hu Q, Negishi EI Highly efficient and selective synthesis of conjugated triynes and higher oligoynes of biological and materials chemical interest via palladium-catalyzed alkynyl-alkenyl coupling ORGANIC LETTERS. 2006 DEC 7; 8 (25): 5773-5776	1	13	9	37
70	375 Huang ZH, Tan Z, Novak T, Zhu GG, et al. Zirconium-catalyzed asymmetric carboalumination of alkenes: ZACA-lipase-catalyzed acetylation synergy ADVANCED SYNTHESIS & CATALYSIS. 2007 MAR; 349 (4-5): 539-545	5	6	14	37
#	Date / Author / Journal	LCS	GCS	LCR	CR
71	208 Negishi EI, NGUYEN T, BOARDMAN LD, SAWADA H, et al. CYCLIZATION REACTIONS OF OMEGA-TOSYLOXY-1-ALKYNYLBORATES AND OMEGA-TOSYLOXY-1-ALKENYLBORATES AND THEIR OMEGA-HALO ANALOGS HETEROATOM CHEMISTRY. 1992 JUN; 3 (3): 293-302	0	5	8	36
72	334 Qian MX, Negishi EI Strictly "pair"-selective and economical synthesis of conjugated diynes via Pd-catalyzed reaction of terminal alkynes with 1,1-dichloroethylene, elimination with LDA, and subsequent transformations ORGANIC PROCESS RESEARCH & DEVELOPMENT. 2003 MAY-JUN; 7 (3): 412-417	3	7	4	36
73	365 Yin N, Wang G, Qian MX, Negishi EI Stereoselective synthesis of the side chains of mycolactones A and B featuring stepwise double substitutions of 1,1-dibromo-1-alkenes ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2006; 45 (18): 2916-2920	3	13	11	36
74	287 Negishi EI, Alimardanov A, Xu CD An efficient and stereoselective synthesis of xerulin via Pd-catalyzed cross coupling and lactonization featuring (E)-iodobromoethylene as a novel two-carbon synthon ORGANIC LETTERS. 2000 JAN; 2 (1): 65-67	13	40	9	35
75	368 Liang B, Novak T, Tan Z, Negishi EI Catalytic, efficient, and syn-selective construction of deoxypolypropionates and other chiral compounds via Zr-catalyzed asymmetric carboalumination of allyl alcohol JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2006 MAR 8; 128 (9): 2770-2771	8	24	10	35
76	43 BROWN HC, NEGISHI EI, KATZ JJ HYDROBORATION .37. STRUCTURAL STUDY OF HYDROBORATION OF OLEFINS WITH THEXYLBORANE IN MOLAR RATIO OF 1=1 - CONVENIENT SYNTHESIS OF THEXYLMONOALKYLBORANES AND THEIR READY CONVERSION TO MONOALKYLBORANES JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1975; 97 (10): 2791-2798	4	40	14	34
77	191 Negishi EI, YOSHIDA T, ABRAMOVITCH A, LEW G, et al. HIGHLY STEREOSELECTIVE SYNTHESES OF CONJUGATED E,E-DIENES AND E,Z-DIENES, E-ENYNES AND E-1,2,3-BUTATRIENES VIA ALKENYLBORANE DERIVATIVES TETRAHEDRON. 1991 JAN 14; 47 (3): 343-356	0	28	4	34
78	234 KONDAKOV DY, Negishi EI ZIRCONIUM-CATALYZED ENANTIOSELECTIVE METHYLALUMINATION OF MONOSUBSTITUTED ALKENES JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1995 NOV 1; 117 (43): 10771-10772	25	88	4	34
79	265 Negishi EI, Makabe H, Shimoyama I, Wu GZ, et al. Catalytic generation and trapping of acylmetals containing Ni and Cu with enolates TETRAHEDRON. 1998 FEB 12; 54 (7): 1095-1106	1	8	12	34
80	97 MATSUSHITA H, Negishi EI PALLADIUM-CATALYZED REACTIONS OF ALLYLIC ELECTROPHILES WITH ORGANO-METALLIC REAGENTS - A REGIOSELECTIVE 1,4-ELIMINATION AND A REGIO-AND STEREOSELECTIVE REDUCTION OF ALLYLIC DERIVATIVES JOURNAL OF ORGANIC CHEMISTRY. 1982; 47 (21): 4161-4165	1	65	4	33
#	Date / Author / Journal	LCS	GCS	LCR	CR
81	213 Negishi EI, AY M, GULEVICH YV, NODA Y HIGHLY STEREOSELECTIVE AND GENERAL-SYNTHESIS OF (Z)-3-METHYL-2-ALKEN-1-OLS VIA PALLADIUM-CATALYZED CROSS COUPLING OF (Z)-3-IODO-2-BUTEN-1-OL WITH ORGANOZINCS AND OTHER ORGANOMETALS TETRAHEDRON LETTERS. 1993 FEB 26; 34 (9): 1437-1440	5	44	9	33
82	240 Negishi EI, Ma SM, Amanfu J, Coperet C, et al. Palladium-catalyzed cyclization of 1-iodo-substituted 1,4-, 1,5-, and 1,6-dienes as well as of 5-iodo-1,5-dienes in the presence of carbon monoxide JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1996 JUN 26; 118 (25): 5919-5931	5	44	16	33
83	306 Negishi EI, Huo SQ Zirconium-catalyzed enantioselective carboalumination of "unactivated" alkenes as a new synthetic tool for asymmetric carbon-carbon bond formation PURE AND APPLIED CHEMISTRY. 2002 JAN; 74 (1): 151-157	1	2	13	33
84	363 Negishi EI, Shi JC, Zeng XZ Palladium-catalyzed trans-selective alkynylation-alkylation tandem process for the synthesis of (E)-3-alkyl-1-trialkylsilyl-3-alken-1-ynes TETRAHEDRON. 2005 OCT 10; 61 (41): 9886-9895	1	7	7	33
85	15 BROWN HC, NEGISHI EI, BURKE PL ORGANOBORANES .12. HYDROBORATION OF 1,3-BUTADIENE WITH BORANE IN TETRAHYDROFURAN IN A RATIO EQUAL TO OR SMALLER THAN 1 1 - INTERCONVERSIN BETWEEN B-ALKYLBOROLANES AND 1,2-TETRAMETHYLENEDIBORANES JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1971; 93 (14): 3400-&	7	15	3	32
86	114 MILLER JA, Negishi EI CONTROLLED CARBOMETALATION .17. CYCLIC CARBOALUMINATION OF ALKYNYLSILANES FORMING EXOCYCLIC ALKENES ISRAEL JOURNAL OF CHEMISTRY. 1984; 24 (2): 76-81	14	41	8	32
87	137 Negishi EI, ZHANG Y, CEDERBAUM FE, WEBB MB A SELECTIVE METHOD FOR THE SYNTHESIS OF STEREODEFINED EXOCYCLIC ALKENES VIA ALLYLMETALATION OF PROPARGYL ALCOHOLS JOURNAL OF ORGANIC CHEMISTRY. 1986 OCT 17; 51 (21): 4080-4082	13	52	5	32
88	307 Negishi EI, Liou SY, Xu CD, Huo SQ A novel, highly selective, and general methodology for the synthesis of 1,5-diene-containing oligoisoprenoids of all possible geometrical combinations exemplified by an iterative and convergent synthesis of coenzyme Q(10) ORGANIC LETTERS. 2002 JAN 24; 4 (2): 261-264	6	25	13	32
89	357 Huang ZH, Qian MX, Babinski DJ, Negishi EI Palladium-catalyzed cross-coupling reactions with zinc, boron, and indium exhibiting high turnover numbers (TONs): Use of bidentate phosphines and other critical factors in achieving high TONs ORGANOMETALLICS. 2005 FEB 14; 24 (4): 475-478	5	21	6	32
90	369 Tan Z, Negishi EI Selective synthesis of epolactaene featuring efficient construction of methyl (Z)-2-iodo-2-butenoate and (2R,3S,4S)-2-trimethylsilyl-2,3-epoxy-4-methyl-gamma-butyrolactone ORGANIC LETTERS. 2006 JUN 22; 8 (13): 2783-2785	1	3	14	32
#	Date / Author / Journal	LCS	GCS	LCR	CR
91	380 Zhang L, Huang Z, Chen WZ, Negishi EI, et al. Negishi coupling-expedient formation of biphenyls on the periphery of inorganic/organometallic diruthenium species ORGANOMETALLICS. 2007 DEC 17; 26 (26): 6526-6528	0	0	2	32
92	241 Pour M, Negishi EI A selective procedure for alpha-alkenylation of enones involving Pd-catalyzed alkenyl-alkenyl coupling and its application to a convergent and efficient synthesis of nakienone B TETRAHEDRON LETTERS. 1996 JUL 1; 37 (27): 4679-4682	7	21	4	31
93	313 Anastasia L, Xu C, Negishi EI Catalytic and selective conversion of (Z)-2-en-4-ynoic acids to either 2H-pyran-2-ones in the presence of ZnBr2 or (Z)-5-alkylidenefuran-2(5H)-ones in the presence of Ag2CO3 TETRAHEDRON LETTERS. 2002 AUG 5; 43 (32): 5673-5676	1	34	11	31
94	8 BROWN HC, NEGISHI EI, GUPTA SK ORGANOBORANES .9. STRUCTURE OF ORGANOBORANES FORMED IN REACTION OF 1,3-BUTADIENE AND DIBORANE IN STOICHIOMETRIC RATIO - AN UNUSUAL THERMAL ISOMERIZATION OF THESE ORGANOBORANES JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1970; 92 (8): 2460-+	10	25	4	30
95	80 KOBAYASHI M, NEGISHI EI A PALLADIUM-CATALYZED STEREOSPECIFIC SUBSTITUTION-REACTION OF HOMOALLYLZINCS WITH BETA-BROMO-SUBSTITUTED ALPHA,BETA-UNSATURATED CARBONYL DERIVATIVES - A HIGHLY SELECTIVE SYNTHESIS OF MOKUPALIDE JOURNAL OF ORGANIC CHEMISTRY. 1980; 45 (25): 5223-5225	19	105	5	30
96	148 Negishi EI, TAKAHASHI T, AKIYOSHI K PALLADIUM-CATALYZED OR PALLADIUM-PROMOTED REDUCTIVE CARBON CARBON COUPLING - EFFECTS OF PHOSPHINES AND CARBON LIGANDS JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1987 NOV 3; 334 (1-2): 181-194	4	38	4	30
97	197 Negishi EI, OWCZARCZYK ZR, SWANSON DR STRICTLY REGIO-CONTROLLED METHOD FOR ALPHA-ALKENYLATION OF CYCLIC-KETONES VIA PALLADIUM-CATALYZED CROSS COUPLING TETRAHEDRON LETTERS. 1991 AUG 26; 32 (35): 4453-4456	11	65	8	30
98	299 Akira K, Negishi EI, Imachi M, Hashimoto T Direct nuclear magnetic resonance spectroscopic analysis of C-13-labeled antipyrine metabolites in human urine DRUG METABOLISM AND DISPOSITION. 2001 JUN; 29 (6): 903-907	0	6	2	30
99	383 Zhu GG, Liang B, Negishi EI Efficient and selective synthesis of (S,R,R,S,R,S)-4,6,8,10,16,18-hexamethyl-docosane via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction) ORGANIC LETTERS. 2008 MAR 20; 10 (6): 1099-1101	1	3	13	30
100	220 Negishi EI, COPERET C, SUGIHARA T, SHIMOYAMA I, et al. PALLADIUM-CATALYZED CARBONYLATIVE CYCLIZATION VIA TRAPPING OF ACYLPALLADIUM DERIVATIVES WITH INTERNAL ENOLATES - ITS SCOPE AND FACTORS AFFECTING THE C-TO-O RATIO TETRAHEDRON. 1994 JAN 10; 50 (2): 425-436	7	25	10	29

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47 Negishi EI, KULKARNI SU, BROWN HC

ORGANOBORANE HETEROCYCLES VIA CYCLIC HYDROBORATION OF DIENES

HETEROCYCLES. 1976; 5: 883-904

246 Negishi EI, Kondakov DY, Choueiry D, Kasai K, et al.

Multiple mechanistic pathways for zirconium-catalyzed carboalumination of alkynes. Requirements for cyclic carbometalation processes involving C-H activation

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1996 OCT 9; 118 (40): 9577-9588

349 Qian MX, Huang ZH, Negishi EI

Use of lnCl(3) as a cocatalyst and a Cl2Pd(DPEphos)-P(2-Furyl)(3) catalyst system for one-pot hydrometalation-cross-coupling and carbometalation-cross-coupling tandem processes

ORGANIC LETTERS. 2004 MAY 13; 6 (10): 1531-1534

201 TAKAHASHI T, HASEGAWA M, SUZUKI N, SABURI M, et al.

ZIRCONIUM-CATALYZED, HIGHLY REGIOSELECTIVE HYDROSILATION REACTION OF ALKENES AND X-RAY STRUCTURES OF SILYL(HYDRIDO)ZIRCONOCENE DERIVATIVES

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1991 OCT 23; 113 (22): 8564-8566

107

302 Anastasia L, Negishi EI

Highly satisfactory procedures for the Pd-catalyzed cross coupling of aryl electrophiles with in situ generated alkynylzinc derivatives

ORGANIC LETTERS. 2001 OCT 4; 3 (20): 3111-3113

336 Shi JC, Zeng XZ, Negishi EI

Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd((Bu3P)-Bu-t)(2)

ORGANIC LETTERS. 2003 MAY 29; 5 (11): 1825-1828

353 Zeng XZ, Zeng FX, Negishi EI

Efficient and selective synthesis of 6,7-dehydrostipiamide via Zr-catalyzed asymmetric carboalumination and Pd-catalyzed cross-coupling of organozincs

ORGANIC LETTERS. 2004 SEP 16; 6 (19): 3245-3248

89 MATSUSHITA H, Negishi EI

SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS .18. PALLADIUM-CATALYZED STEREOSPECIFIC AND REGIOSPECIFIC COUPLING OF ALLYLIC DERIVATIVES WITH ALKENYLMETALS AND ARYLMETALS - A HIGHLY SELECTIVE SYNTHESIS OF 1,4-DIENES

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1981; 103 (10): 2882-2884

170 WU GZ, LAMATY F, Negishi EI

METAL-PROMOTED CYCLIZATION .26. PALLADIUM-CATALYZED CYCLIZATION OF BENZYL HALIDES AND RELATED ELECTROPHILES CONTAINING ALKENES AND ALKYNES AS A NOVEL ROUTE TO CARBOCYCLES

JOURNAL OF ORGANIC CHEMISTRY. 1989 MAY 26; 54 (11): 2507-2508

247 Negishi EI, Liu F, Choueiry D, Mohamud MM, et al.

Convenient and general synthesis of 1-monoorganyl-and 1,2-diorganylcyclobutenes via cyclialkylation

JOURNAL OF ORGANIC CHEMISTRY. 1996 NOV 15; 61 (23): 8325-8328

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285 Akira K, Negishi EI, Sakuma C, Hashimoto T

Direct detection of antipyrine metabolites in rat urine by C-13 labeling and NMR spectroscopy

DRUG METABOLISM AND DISPOSITION. 1999 NOV; 27 (11): 1248-1253

379 Huang ZH, Negishi EI

Highly stereo-and regioselective synthesis of (Z)-trisubstituted Alkenes via 1-bromo-1-alkyne hydroboration-migratory insertion-Zn-promoted iodinolysis and Pd-catalyzed organozinc cross-coupling

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2007 NOV 28; 129 (47): 14788-14792

218 TAKAHASHI T, AOYAGI K, DENISOV V, SUZUKI N, et al.

ZIRCONIUM CATALYZED C-C BOND FORMATION REACTION OF CONJUGATED DIYNES WITH ETMGBR

TETRAHEDRON LETTERS. 1993 DEC 17; 34 (51): 8301-8304

343 Dumond YR, Negishi EI

Zr-promoted 'pair'-selective and regioselective synthesis of penta-substituted benzene derivatives

TETRAHEDRON. 2004 FEB 2; 60 (6): 1345-1352

384 Wang GW, Huang ZH, Negishi EI

Efficient and selective syntheses of (all-E)- and (6E,10Z)-2 '-O-Methylmyxalamides D via Pd-catalyzed alkenylation-carbonyl olefination synergy

ORGANIC LETTERS. 2008 AUG 7; 10 (15): 3223-3226

385 Xu Z, Negishi EI

Efficient and stereoselective synthesis of yellow scale pheromone via alkyne haloboration, Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction), and Pd-catalyzed tandem Negishi coupling

ORGANIC LETTERS. 2008 OCT 2; 10 (19): 4311-4314

138 BROWN HC, BASAVAIAH D, KULKARNI SU, LEE HD, et al.

VINYLIC ORGANOBORANES .6. A GENERAL-SYNTHESIS OF (E)-DISUBSTITUTED ALKENES OR KETONES VIA THE (E)-(1-SUBSTITUTED-1-ALKENYL)BORONIC ESTERS

JOURNAL OF ORGANIC CHEMISTRY. 1986 DEC 26; 51 (26): 5270-5276

255 Negishi EI, Ma SM, Sugihara T, Noda Y

Synthesis of hydrazulenes via Zr-promoted bicyclization of enynes and transition metal-catalyzed or radical cyclization of alkenyl iodides. Efficient synthesis of (+/-)-7-epi-beta-bulnesene

JOURNAL OF ORGANIC CHEMISTRY. 1997 APR 4; 62 (7): 1922-1923

373 Metay E, Hu Q, Negishi EI

Highly efficient and selective synthesis of conjugated triynes and higher oligoynes of biological and materials chemical interest via palladium-catalyzed alkynyl-alkenyl coupling

ORGANIC LETTERS. 2006 DEC 7; 8 (25): 5773-5776

375 Huang ZH, Tan Z, Novak T, Zhu GG, et al.

Zirconium-catalyzed asymmetric carboalumination of alkenes: ZACA-lipase-catalyzed acetylation synergy

ADVANCED SYNTHESIS & CATALYSIS. 2007 MAR; 349 (4-5): 539-545

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208 Negishi EI, NGUYEN T, BOARDMAN LD, SAWADA H, et al.

CYCLIZATION REACTIONS OF OMEGA-TOSYLOXY-1-ALKYNYLBORATES AND OMEGA-TOSYLOXY-1-ALKENYLBORATES AND THEIR OMEGA-HALO ANALOGS

HETEROATOM CHEMISTRY. 1992 JUN; 3 (3): 293-302

334 Qian MX, Negishi EI

Strictly "pair"-selective and economical synthesis of conjugated diynes via Pd-catalyzed reaction of terminal alkynes with 1,1-dichloroethylene, elimination with LDA, and subsequent transformations

ORGANIC PROCESS RESEARCH & DEVELOPMENT. 2003 MAY-JUN; 7 (3): 412-417

365 Yin N, Wang G, Qian MX, Negishi EI

Stereoselective synthesis of the side chains of mycolactones A and B featuring stepwise double substitutions of 1,1-dibromo-1-alkenes

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2006; 45 (18): 2916-2920

287 Negishi EI, Alimardanov A, Xu CD

An efficient and stereoselective synthesis of xerulin via Pd-catalyzed cross coupling and lactonization featuring (E)-iodobromoethylene as a novel two-carbon synthon

ORGANIC LETTERS. 2000 JAN; 2 (1): 65-67

368 Liang B, Novak T, Tan Z, Negishi EI

Catalytic, efficient, and syn-selective construction of deoxypolypropionates and other chiral compounds via Zr-catalyzed asymmetric carboalumination of allyl alcohol

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2006 MAR 8; 128 (9): 2770-2771

43 BROWN HC, NEGISHI EI, KATZ JJ

HYDROBORATION .37. STRUCTURAL STUDY OF HYDROBORATION OF OLEFINS WITH THEXYLBORANE IN MOLAR RATIO OF 1=1 - CONVENIENT SYNTHESIS OF THEXYLMONOALKYLBORANES AND THEIR READY CONVERSION TO MONOALKYLBORANES

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1975; 97 (10): 2791-2798

191 Negishi EI, YOSHIDA T, ABRAMOVITCH A, LEW G, et al.

HIGHLY STEREOSELECTIVE SYNTHESES OF CONJUGATED E,E-DIENES AND E,Z-DIENES, E-ENYNES AND E-1,2,3-BUTATRIENES VIA ALKENYLBORANE DERIVATIVES

TETRAHEDRON. 1991 JAN 14; 47 (3): 343-356

234 KONDAKOV DY, Negishi EI

ZIRCONIUM-CATALYZED ENANTIOSELECTIVE METHYLALUMINATION OF MONOSUBSTITUTED ALKENES

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1995 NOV 1; 117 (43): 10771-10772

265 Negishi EI, Makabe H, Shimoyama I, Wu GZ, et al.

Catalytic generation and trapping of acylmetals containing Ni and Cu with enolates

TETRAHEDRON. 1998 FEB 12; 54 (7): 1095-1106

97 MATSUSHITA H, Negishi EI

PALLADIUM-CATALYZED REACTIONS OF ALLYLIC ELECTROPHILES WITH ORGANO-METALLIC REAGENTS - A REGIOSELECTIVE 1,4-ELIMINATION AND A REGIO-AND STEREOSELECTIVE REDUCTION OF ALLYLIC DERIVATIVES

JOURNAL OF ORGANIC CHEMISTRY. 1982; 47 (21): 4161-4165

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LCR

213 Negishi EI, AY M, GULEVICH YV, NODA Y

HIGHLY STEREOSELECTIVE AND GENERAL-SYNTHESIS OF (Z)-3-METHYL-2-ALKEN-1-OLS VIA PALLADIUM-CATALYZED CROSS COUPLING OF (Z)-3-IODO-2-BUTEN-1-OL WITH ORGANOZINCS AND OTHER ORGANOMETALS

TETRAHEDRON LETTERS. 1993 FEB 26; 34 (9): 1437-1440

240 Negishi EI, Ma SM, Amanfu J, Coperet C, et al.

Palladium-catalyzed cyclization of 1-iodo-substituted 1,4-, 1,5-, and 1,6-dienes as well as of 5-iodo-1,5-dienes in the presence of carbon monoxide

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1996 JUN 26; 118 (25): 5919-5931

306 Negishi EI, Huo SQ

Zirconium-catalyzed enantioselective carboalumination of "unactivated" alkenes as a new synthetic tool for asymmetric carbon-carbon bond formation

PURE AND APPLIED CHEMISTRY. 2002 JAN; 74 (1): 151-157

363 Negishi EI, Shi JC, Zeng XZ

Palladium-catalyzed trans-selective alkynylation-alkylation tandem process for the synthesis of (E)-3-alkyl-1-trialkylsilyl-3-alken-1-ynes

TETRAHEDRON. 2005 OCT 10; 61 (41): 9886-9895

15 BROWN HC, NEGISHI EI, BURKE PL

ORGANOBORANES .12. HYDROBORATION OF 1,3-BUTADIENE WITH BORANE IN TETRAHYDROFURAN IN A RATIO EQUAL TO OR SMALLER THAN 1 1 - INTERCONVERSIN BETWEEN B-ALKYLBOROLANES AND 1,2-TETRAMETHYLENEDIBORANES

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1971; 93 (14): 3400-&

114 MILLER JA, Negishi EI

CONTROLLED CARBOMETALATION .17. CYCLIC CARBOALUMINATION OF ALKYNYLSILANES FORMING EXOCYCLIC ALKENES

ISRAEL JOURNAL OF CHEMISTRY. 1984; 24 (2): 76-81

137 Negishi EI, ZHANG Y, CEDERBAUM FE, WEBB MB

A SELECTIVE METHOD FOR THE SYNTHESIS OF STEREODEFINED EXOCYCLIC ALKENES VIA ALLYLMETALATION OF PROPARGYL ALCOHOLS

JOURNAL OF ORGANIC CHEMISTRY. 1986 OCT 17; 51 (21): 4080-4082

307 Negishi EI, Liou SY, Xu CD, Huo SQ

A novel, highly selective, and general methodology for the synthesis of 1,5-diene-containing oligoisoprenoids of all possible geometrical combinations exemplified by an iterative and convergent synthesis of coenzyme Q(10)

ORGANIC LETTERS. 2002 JAN 24; 4 (2): 261-264

357 Huang ZH, Qian MX, Babinski DJ, Negishi EI

Palladium-catalyzed cross-coupling reactions with zinc, boron, and indium exhibiting high turnover numbers (TONs): Use of bidentate phosphines and other critical factors in achieving high TONs

ORGANOMETALLICS. 2005 FEB 14; 24 (4): 475-478

369 Tan Z, Negishi EI

Selective synthesis of epolactaene featuring efficient construction of methyl (Z)-2-iodo-2-butenoate and (2R,3S,4S)-2-trimethylsilyl-2,3-epoxy-4-methyl-gamma-butyrolactone

ORGANIC LETTERS. 2006 JUN 22; 8 (13): 2783-2785

Date / Author / Journal

LCS

GCS

LCR

380 Zhang L, Huang Z, Chen WZ, Negishi EI, et al.

Negishi coupling-expedient formation of biphenyls on the periphery of inorganic/organometallic diruthenium species

ORGANOMETALLICS. 2007 DEC 17; 26 (26): 6526-6528

241 Pour M, Negishi EI

A selective procedure for alpha-alkenylation of enones involving Pd-catalyzed alkenyl-alkenyl coupling and its application to a convergent and efficient synthesis of nakienone B

TETRAHEDRON LETTERS. 1996 JUL 1; 37 (27): 4679-4682

313 Anastasia L, Xu C, Negishi EI

Catalytic and selective conversion of (Z)-2-en-4-ynoic acids to either 2H-pyran-2-ones in the presence of ZnBr2 or (Z)-5-alkylidenefuran-2(5H)-ones in the presence of Ag2CO3

TETRAHEDRON LETTERS. 2002 AUG 5; 43 (32): 5673-5676

8 BROWN HC, NEGISHI EI, GUPTA SK

ORGANOBORANES .9. STRUCTURE OF ORGANOBORANES FORMED IN REACTION OF 1,3-BUTADIENE AND DIBORANE IN STOICHIOMETRIC RATIO - AN UNUSUAL THERMAL ISOMERIZATION OF THESE ORGANOBORANES

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 1970; 92 (8): 2460-+

80 KOBAYASHI M, NEGISHI EI

A PALLADIUM-CATALYZED STEREOSPECIFIC SUBSTITUTION-REACTION OF HOMOALLYLZINCS WITH BETA-BROMO-SUBSTITUTED ALPHA,BETA-UNSATURATED CARBONYL DERIVATIVES - A HIGHLY SELECTIVE SYNTHESIS OF MOKUPALIDE

JOURNAL OF ORGANIC CHEMISTRY. 1980; 45 (25): 5223-5225

105

148 Negishi EI, TAKAHASHI T, AKIYOSHI K

PALLADIUM-CATALYZED OR PALLADIUM-PROMOTED REDUCTIVE CARBON CARBON COUPLING - EFFECTS OF PHOSPHINES AND CARBON LIGANDS

JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1987 NOV 3; 334 (1-2): 181-194

197 Negishi EI, OWCZARCZYK ZR, SWANSON DR

STRICTLY REGIO-CONTROLLED METHOD FOR ALPHA-ALKENYLATION OF CYCLIC-KETONES VIA PALLADIUM-CATALYZED CROSS COUPLING

TETRAHEDRON LETTERS. 1991 AUG 26; 32 (35): 4453-4456

299 Akira K, Negishi EI, Imachi M, Hashimoto T

Direct nuclear magnetic resonance spectroscopic analysis of C-13-labeled antipyrine metabolites in human urine

DRUG METABOLISM AND DISPOSITION. 2001 JUN; 29 (6): 903-907

383 Zhu GG, Liang B, Negishi EI

Efficient and selective synthesis of (S,R,R,S,R,S)-4,6,8,10,16,18-hexamethyl-docosane via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction)

ORGANIC LETTERS. 2008 MAR 20; 10 (6): 1099-1101

100

220 Negishi EI, COPERET C, SUGIHARA T, SHIMOYAMA I, et al.

PALLADIUM-CATALYZED CARBONYLATIVE CYCLIZATION VIA TRAPPING OF ACYLPALLADIUM DERIVATIVES WITH INTERNAL ENOLATES - ITS SCOPE AND FACTORS AFFECTING THE C-TO-O RATIO

TETRAHEDRON. 1994 JAN 10; 50 (2): 425-436

Publications by EI Negishi Publications by EI Negishi	Historiographs	Glossary HistCite Guide About Grand Totals: LCS 2472, GCS 18747, CR 10274 Means: LCS 6.40, GCS 48.57, CR 26.62 Collection span: 1965 - 2008
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