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Author(s): Hamers RJ; Coulter SK; Ellison MD; Hovis JS; Padowitz DF; Schwartz MP; Greenlief CM; Russell JN
Title: Cycloaddition chemistry of organic molecules with semiconductor surfaces
Source: ACCOUNTS OF CHEMICAL RESEARCH 33 (9): 617-624
Date: 2000 SEP
Document Type: Journal : Review
DOI:
Language: English
Comment:
Address: Univ Wisconsin, Dept Chem, Madison, WI 53706 USA.
Univ Missouri, Dept Chem, Columbia, MO 65211 USA. USN, Res Lab, Div Chem, Washington, DC 20375 USA. Reprint: Hamers, RJ, Univ Wisconsin, Dept Chem, 1101 Univ Ave, Madison, WI 53706
USA. E-mail:
Abstract: Recent investigations have shown that cycloaddition reactions, widely used in organic chemistry to form ring compounds, can also be applied to link organic molecules to the (001) surfaces of crystalline silicon, germanium, and diamond. While these surfaces are comprised of Si=Si, Ge=Ge, and C=C structural units that resemble the C=C bonds of organic alkenes, the rates and mechanisms of the surface reactions show some distinct differences from those of their organic counterparts This article reviews recent studies of [2 + 2], [4 + 2] Diels-Alder, and other cycloaddition reactions of organic molecules with semiconductor surfaces and summarizes the current understanding of the reaction pathways.
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