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Author(s): Fogg DE; dos Santos EN
Title: Tandem catalysis: a taxonomy and illustrative review
Source: COORDINATION CHEMISTRY REVIEWS 248 (21-24): 2365-2379
Date: 2004 DEC
Document Type: Journal : Review
DOI:
Language: English
Comment:
Address: Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada.
Univ Ottawa, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada. Reprint: Fogg, DE, Univ Ottawa, Dept Chem, 10 Marie Curie, Ottawa, ON K1N 6N5,
Canada. E-mail: dfogg@science.uottawa.ca
nicolau@dedalus.lcc.ufmg.br Author Keywords: catalysis; tandem catalysis; classification; cascade catalysis; domino
catalysis; orthogonal catalysis; olefin metathesis; hydroformylation
KeyWords Plus: ONE-POT SYNTHESIS; RING-CLOSING METATHESIS; MULTIFUNCTIONAL PALLADIUM
CATALYSIS; ALLYLIC ACETATE ISOMERIZATION; RUTHENIUM CARBENE COMPLEXES;
OLEFIN METATHESIS; ORGANIC-SYNTHESIS; CARBONYLATIVE
HYDROAMINOMETHYLATION; HETEROGENEOUS CATALYSIS; CASCADE REACTIONS
Abstract: A scheme is advanced for the classification of one-pot, coupled catalytic transformations, which distinguishes between one-pot, domino/ cascade, and tandem catalysis. The last of these is divided into three subclasses: orthogonal, auto-tandem, and assisted tandem catalysis. The proposed taxonomy, and the potential of tandem catalysis in organic synthesis, are illustrated with examples drawn from olefin metathesis and hydroformylation chemistry. (C) 2004 Elsevier B.V. All rights reserved.
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